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Enable Built-in Content Filtering
Enforce Screen Time on your Managed Mac to add another layer of filtering.
Tech Lockdown Team
Built-in content filtering allows you to block content even when a VPN is enabled. A Content Filter will filter content before it is processed by a DNS Filter, so it's a great extra blocking layer.
Once the profile is distributed, the content filter should start blocking websites.
Note
In the above screenshot, it seems like you can click "Add Website" to quickly unblock a website. However, I've found that this doesn't actually work. If for some reason you can easily unblock a website, restrict access to Screen Time by following the Customize System Features section of this guide.
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Configure browsers and browser extensions:
Configure Browsers
Configure Browsers
Configure different settings on your Browser to prevent filter bypass.